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Environ Eng Res > Volume 23(1); 2018 > Article
Li, Tang, Fan, Zhou, and Yang: Assessment and comparison of three different air quality indices in China


Air pollution index (API) is used in Mainland China and includes only SO2, NO2 and PM10. In 2016, air quality index (AQI) replaced API. AQI contains three more air pollutants (CO, O3 and PM2.5). Both the indices emphasize on the effect of a single pollutant, whereas the contributions of all other pollutants are ignored. Therefore, in the present work, a novel air quality index (NAQI), which emphasizes on all air pollutants, has been introduced for the first time. The results showed that there were 19 d (5.2%) in API, 28 d (7.7%) in AQI and 183 d (50.1%) in NAQI when the indices were more than 100. In API, PM10 and SO2 were regarded as the primary pollutants, whereas all five air pollutants in AQI were regarded as primary. Furthermore, four air pollutants (other than the CO) in NAQI were regarded as primary pollutants. PM10, as being the primary pollutant, contributed greatly in these air quality indices, and accounted for 51.2% (API), 37.0% (AQI) and 52.6% (NAQI). The results also showed that particulate matter pollution was significantly high in Luzhou, where stricter pollution control measures should be implemented.

1. Introduction

Air is one of those fundamental necessities, without which life cannot exist in its current form. Nevertheless, urban ambient air quality is decreasing due to industrialization and urbanization in China [12]. Periods of haze and dust have made Chinese people feel anxious for the quality of ambient air. In order to keep the citizens informed of the urban air quality, many cities assess air quality through air quality monitoring networks, which continuously record the mass concentrations of different air pollutants [3]. The concentrations of several criteria pollutants can be included in the air pollution index (API), which is easy to be understood by the public. API and air quality index (AQI) have been used to obtain and convey information regarding the urban air quality in a number of countries and zones worldwide [4].
Bodnar et al. [5] used the index methodology proposed by Bruno and Cocchi (BC Indices) to compare the air quality in Italy, Germany and Poland, and proposed to have a unique, unanimous index in Europe. Based upon the relationship between the health risk and the concentrations of different air pollutants, Cairncross et al. [6] developed a novel air pollution index. Cheng et al. [7] revised the air quality index for PM2.5 according to entropy principle, and compared it with Pollutant Standard Index (PSI) and AQI. The revised air quality index (RAQI) not only demonstrated higher accuracy, but also distinguished different pollution episodes. In order to represent the global ambient air quality, Cooper et al. [8] developed a satellite-based multi-pollutant index for the concentrations of PM2.5 and NO2. In short, there are numerous reports in the literature, which detail the comparison and assessment of ambient air quality using different kinds of air pollution or air quality indices [915].
API and AQI usually include several air pollutants, such as SO2, NO2, TSP, PM10, PM2.5, CO, O3, Pb and VOCs. In Mainland China, only three criteria air pollutants, namely the SO2, NO2 and PM10, are used to calculate API, which is based on National Ambient Air Quality Standard (NAAQS, GB3095-1996) that was issued in 1996 [16]. Due to the drastic increase in the number of vehicles, air pollution has become a serious concern due to their exhaust emissions. In the US, Korea, Hong Kong and other countries, CO and O3 have already been included in the API and AQI since past few years [12]. Due to this reason, the Chinese government issued AQI guideline on January 1, 2016, which was strict, objective and accurate for the evaluation of results. Both API and AQI consider only the maximum values of sub-indices, and discard the values of other sub-indices and synergistic effects of other air pollutants [17]. Therefore, an attempt has been made to build a novel air quality index (NAQI), which is based on combined effects and weights of different air pollutants. In this paper, based on the data for the concentrations of five air pollutants collected in 2009 (365 d) in Luzhou, both the comparison and assessment of three different air-quality indices (API, AQI and NAQI) are presented and discussed.

2. Methodology

2.1. Sample Location and Data Collection

There are 5,543 valuable air quality monitoring data points in Luzhou, China. As per 2009, these data points consisted of four monitoring sites (Jiushi Mountain (JS), Xiaoshi Duck (XS), Zhongshan Monitoring Station (ZS), Lantian Bridge (LT)), which extended from north to south across the central part of the city (Fig. 1). Since the JS site is regarded as a background site, the data from this monitoring station was not considered in this work. Average daily mass concentrations of SO2, NO2, PM10, CO and O3 were recorded using ambient air successive auto monitoring. The monitoring methods used were the ones recommended by the Environmental Protection Ministry of China.

2.2. API Calculations

The data were used to calculate the API, whereas the reference scale values are reported in Table 1. The calculation of API was carried out accordingly to Eq. (1) and Eq. (2).
where APIi is the sub-index of pollutant i, ci is the mean concentration of the pollutant i, cl is the break point ≤ ci, ch is the break point > ci, APIh and APIl are the API values when the concentration values are cl and ch (respectively), and n is the number of pollutants. When the API value was less than or equal to 50, the air quality was considered to be good, and nothing was regarded as the primary pollutant. However, when the API value was higher than 50, the pollutant which had the maximum APIi was regarded as the primary pollutant. If the APIi values of air pollutants were the same, the pollutant which was in turn of SO2, NO2, PM10, CO, O3 and PM2.5 was regarded as the primary pollutant.

2.3. AQI Calculations

The method to calculate AQI is the same as API except that the mass concentration limits of these air pollutants were different. The AQI values, their description and corresponding concentrations are listed in Table 1. There are six air pollutants, namely the SO2, NO2, PM10, CO, O3 and PM2.5. The concentration data of PM2.5 was not included as PM2.5 sub-index was not considered for calculating AQI, and thus was not monitored. This shortcoming was rectified as the mass concentration of PM2.5 was started to be monitored from October 2013 onwards.

2.4. NAQI Calculations

Both API and AQI are based on the concentration limits of air pollutants. However, AQI is easier to be understood. Furthermore, more countries and regions of the world use AQI to get information on the ambient urban air quality. The complexity of the calculating method and disregarding other air pollutants besides the ones having highest API or AQI values are the main shortcomings of API and AQI indices [18]. The process of calculating AQI is shown in Fig. 2. In fact, the mass concentration limits of air pollutants are very important. When AQI or API value was less than 100, the limit value was equal to Grade-II mass concentration value in the National Ambient Air Quality Standard (NAAQS, GB3095-2012), as listed in Table 2. With improvement of environmental quality and the enhancement of environmental consciousness, the NAAQS has become stricter and more scientific. In this way, the AQI values became higher, and more significant changes in air quality were observed. The modified NAAQS is divided into six grades, which makes the calculation of AQI a little difficult. On the other hand, the final AQI value of some city or site might be the highest among all the AQIi values. In such a circumstance, the effect of air pollutant having the maximum AQIi value on human health also covers the effects of all other air pollutants [19]. For example, when AQIso2, AQINO2, and AQIPM10 had values of 119, 110, 120, respectively, the AQI value was considered to be 120. The calculating method of AQI is the same as that of the API. Therefore, the PM10 is the primary pollutant among three air pollutants, whereas the SO2, and NO2 are ignored. However, it is widely accepted that both the SO2 and NO2 can have deteriorating impact on the health of humans.
In order to remove these shortcomings in the AQI, a NAQI was introduced in the current study [20]. Eq. (3)Eq. (5) were used to calculate NAQI.
where NAQI is the AQI of a city or a site, Wi is the weight of the pollutant i, Pi is the index of the pollutant i, ci is the mean concentration of the pollutant i, and si is the mass concentration value of the pollutant i for Grade-I in NAAQS, respectively. When the API or AQI value was higher than 50, the pollutant which had the maximum APIi or AQIi value was regarded as the primary pollutant. If the APIi or AQIi values of air pollutants were the same, the pollutant that was in turn of SO2, NO2, PM10, CO, O3 and PM2.5 was regarded as the primary pollutant. As long as the Pi of a pollutant was more than 1.0, the pollutant was regarded as the primary pollutant in NAQI. Eq. (5) was used to calculate Pi. Similarly, all those pollutants, which had a Pi value of more than 1.0, were considered as the primary pollutants.

3. Results and Discussion

3.1. Variation in Ambient Air Quality

Fig. 2 shows the annual mean mass concentrations of five air pollutants. The mean concentrations of SO2, NO2, PM10, CO and O3 were 59 ± 27, 40 ± 12, 72 ± 40, 2,017 ± 801 and 54 ± 31 μg/m3, respectively. The concentrations of SO2, and NO2 were very close to Grade-II annual mean concentrations of 60 μg/m3 and 40 μg/m3, respectively. The concentrations of other three pollutants were much lower than their corresponding annual mean concentration limit values. The concentrations of SO2, CO and O3 were substantially higher than those reported for big cities, such as Beijing, Shanghai, Guangzhou, Chengdu, and Seoul (Table 3). This could be due to the burning of coal in industry, which has high sulfur ratio. On the contrary, the mass concentrations of NO2 were lower than those in Beijing, Shanghai, Guangzhou, Chengdu, and Seoul. It was demonstrated that the air pollution from the exhausts of vehicles was not the main source of pollution in these cities.
In general, the trends for monthly mean concentrations of SO2, NO2, PM10 and CO were similar to those for the annual concentrations, as shown in Fig. 3. The mass concentrations of these pollutants were higher in winter and spring than those in summer and autumn, as observed by Wan et al. [21]. However, the variation in O3 concentration showed a different trend, in which, the concentrations were lower in colder months than in the hotter ones. Lu et al. [12] obtained similar results for monthly variations in pollutants’ concentrations in Hong Kong. The seasonal variations can be explained by the combined influence of high temperature, rainy weather, and unstable atmospheric conditions in summer, whereas these were caused by low temperature, dry weather and more stable atmospheric conditions during winter.

3.2. Comparison of Different Air Quality Indices

API includes only SO2, NO2 and PM10, whereas AQI includes two more criteria pollutants (CO and O3) on top of the ones present in API. The corresponding mass concentration of NO2 was different between the API and AQI indices. The NO2 concentration was 40 μg/m3, and 80 μg/m3 for Grade-I and Grade-II in AQI, respectively, whereas the values for NO2 mass concentration in API were 80 μg/m3 and 120 μg/m3 for Grade-I and Grade-II, respectively. NAQI also consists of five air pollutants, namely the SO2, NO2, PM10, CO, and O3. However, the corresponding mass concentrations of these five air pollutants were only based on the daily average concentrations in Grade-I of NAAQS. The contributions of these five air pollutants to air quality were considered in NAQI and emphasized on the importance of NAAQS.
According to 2009 air quality monitoring data in Luzhou, three different air-quality indices were calculated on daily basis. According to the API values, the number of days monitored were 99, 247 and 19 for Grades I, II and III, respectively. The number of days for which the air quality was good and/or moderate was 346 (94.8%). This means that, the number of days when API > 100 accounted for only 5.2% of the total number of days, as shown in Fig. 4. According to AQI values, the number of days were 63, 274 and 28 for Grades I, II and III, respectively. Compared to API, the number of days for good air quality decreased to 36, whereas the number of days for Grades II and III increased to 27 and 9, respectively. The number of days when AQI > 100 was 28 and accounted for 7.7% of the total number of days.
According to NAQI values, the number of days were 23, 159, 116, 44, 22 and 1 for Grades I, II, III, IV, V and VI, respectively. Six grades of air quality were obtained using the NAQI method. According to NAQI values, there were 183 days when NAQI > 100, and these accounted for 50.1% of the total number of days in 2009. The maximum NAQI value was 330, which was observed on November 11, 2009. The mass concentration of PM10 was 4.7 times higher than that of the Grade I concentration of NAAQS. Meanwhile the maximum value for both API and AQI was 144 on the same day in 2009, and were caused by PM10 pollution. This was due to the reason that particulate matter was produced from burning wood in cold days (for heating purposes), due to which, the air diffused weakly. In short, the urban ambient air quality was the best for API, better for AQI and bad for NAQI as per the results obtained in the current work. Similar conclusions were made and reported by Kyrkilis et al. [22]. Therefore, to a certain extent, the fact whether the air quality is good or bad depends on the assessment method used.

3.3. Comparison of the Primary Pollutants

The pollutant of maximum index value was regarded as the primary pollutant when either API or AQI value was more than 50. Meanwhile, SO2, NO2, PM10, CO and O3 were in turn termed as the primary pollutants when their values were the same. The difference is that, all the pollutants with Pi. values of more than 1.0, were regarded as the primary pollutants.
According to the API values of Luzhou in 2009, both SO2 and PM10 were the primary pollutants, whereas NO2 did not appear as the primary pollutant during the time considered in the study, as shown in Fig. 5. There were 79 d and 187 d when they were regarded as the primary pollutants, and accounted for 21.6% and 51.2% of the total days, respectively.
According to the AQI values, all five air pollutants, which were regarded as the primary pollutants, appeared in the results. The days when SO2, NO2, PM10, CO, O3 were regarded as primary pollutants were 52, 26, 135, 57, and 29, respectively. In addition, PM10 accounted for 37.0% of the total days. This value was more than one third of the days for the primary pollutants. It is important to note that NO2 and CO, which were mainly emitted by automobiles, showed up in the results, and accounted for 7.1% and 15.6% of the total days, respectively. In the secondary air pollutants, O3 accounted for 7.9% of the total days, which were 29 d as per the AQI values. The days for which the air quality was “less than good” (API, AQI or NAQI > 50) were more in AQI than in API. There were 302 d in AQI and 266 d in API. This meant that, according to AQI, the ambient air quality became worse and more air pollutants caused air pollution in Luzhou, China. However, the main difference was that more air pollutants were regarded as primary pollutants in AQI. NO2 did not appear in the API as primary pollutant; however, it remained primary pollutant for 26 d in AQI. The reason of the difference was stricter air quality standard set in AQI. The Grade II levels for NO2 were 80 μg/m3 in AQI and 120 μg/m3 in API. Therefore, it can be seen that, for API or AQI, the level of air quality standard and the kinds of air pollutants were very important. An et al. [23] suggested that major efforts need to be made on the standard-setting process to achieve the lowest concentrations for public health priorities. In this regard, the World Health Organization’s (WHO) air quality guidelines are worth referencing.
Since the concentration levels and kinds of air pollutants play a key role in API or AQI indices. Therefore, the effects of air quality standards and all kinds of air pollutants should be emphasized. NAQI takes into account the air quality standards and five air pollutants. The last index value was the maximum for AQI or API, whereas the effects of other air pollutants having smaller values were ignored. In NAQI, the last index value was equal to the sum of sub-NAQI values. There were 342 d when NAQI > 50 in NAQI, which consisted of 192 (52.6%) d for PM10, 98 (26.8%) d for SO2, 27 (7.4%) d for O3 and 25 (6.8%) d for NO2. In addition, CO did not appear as the primary pollutant in NAQI during the time period considered in the current work, although it appeared in AQI. This could be due to the reason that the concentration limits (4,000 μg/m3) for Grades I and II were the same in NAAQS. The mass concentration levels of all other air pollutants were higher than the limit level of Grade-I, while the concentration levels of CO were lower than the limit level of Grade-I. Generally, the primary pollutants were obviously different due to three AQIs.

3.4. Assessment of Three Air Quality Indices

The air quality standard levels in AQI were stricter than those in API. In addition, AQI contained additional air pollutants which could be considered as primary pollutants. Comparing the two indices, NAQI synthesized five air pollutants, such as SO2, NO2, PM10, CO and O3 and were calculated based on the ratio of each air pollutant’s concentration and corresponding first level in NAAQS. According to the calculated results of three AQIs, the trends of daily index values were not different, as shown in Fig. 6. The major difference was that the NAQI values were the greatest in all three AQIs, whereas API values were the minimum. Therefore, the NAQI values can accurately reflect the air quality. The correlation analysis between three AQIs and the concentrations of five criteria air pollutants are listed in Table 4. The air pollutants can be ranked according to decreasing correlation coefficients as PM10, SO2 and NO2. This is mainly due to the reason that the source of pollution is industrial coal combustion and the exhausts from automobiles. However, the correlation coefficients for PM10, SO2 and NO2 concentration are higher in NAQI than those in AQI, and API. These results illustrated that NAQI can accurately reflect the urban ambient air quality due to PM10, SO2 and NO2. According to the correlation coefficients between NAQI, AQI and CO concentrations, AQI can reflect the urban air quality much better than NAQI. This is due to the reason that CO is regarded as a primary pollutant in AQI, and not in NAQI. On the contrary, both NAQI and AQI cannot reflect the O3 concentrations due to secondary pollution. The AQI, which can represent air quality due to second air pollution, should be studied in more details.

4. Conclusions

In China, API consists of SO2, NO2 and PM10 and has been used to inform citizens of the urban ambient air quality since 2000. AQI has additional pollutants of CO, O3 and PM2.5 since 2016. The two kinds of AQIs only consider the maximum index value of an air pollutant, whereas the contributions and combined effects of other air pollutants were ignored. Due to these reasons, NAQI included the combined effects of all air pollutants, and has the advantage to be calculated in a simple way according to NAAQS.
The data of air pollutant concentrations, including SO2, NO2, PM10, CO and O3, were collected daily in 2009 at four environmental monitoring sites in Luzhou, which is a southern city of Sichuan basin in China. The statistical results showed that the annual mass concentrations of SO2, CO, and O3 in Luzhou were higher than those in other big cities (Beijing, Shanghai, Guangzhou, Chengdu, and Seoul). On the contrary, the concentrations of NO2 and PM10 were lower than the values in these big cities. In addition, all air pollutants except O3 had monthly variations, which showed that the concentrations of these pollutants were found to be higher in winter and spring than those in summer and autumn.
According to these air pollutants’ concentration data, three different AQIs of API, AQI and NAQI were compared. The results showed that there were 19 d (5.2% of the total days) in API, 28 d (7.7% of the total days) in AQI and 183 d (50.1% of the total days) in NAQI when these indices were higher than 100. Overall, depending on the NAQI values, the urban air quality became worse. Both PM10 and SO2 in API, all five air pollutants in AQI, and four air pollutants except for the CO in NAQI were regarded as the primary pollutants. PM10 was the main primary pollutant in three AQIs, which accounted for 51.2% (of total days), 37.0% (of total days) and 52.6% (of total days), respectively. Therefore, the particulate matter’s pollution was very significant in Luzhou and stricter pollution control measures should be implemented to control it.
The variation trends of three AQIs were not different, though the daily variation of NAQI in 2009 was always higher than those for the AQI and API. The correlation between NAQI and air pollutants’ concentration was more obvious than the other two indices. Based upon the results, it can safely be said that NAQI can satisfactorily and systematically reflect the urban ambient air quality situation.


This work was supported by the Science & Technology Department of Sichuan Province (2015JY0094, 2017KZ0041), and Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province (CSPC2014-4-2). The authors wish to acknowledge the support obtained from Luzhou Environmental Protection Agency in the form of urban ambient air quality monitoring data.


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Fig. 1
Location of the environmental monitoring sites in Luzhou City.
Fig. 2
Mass concentrations of five air pollutants in Luzhou City.
Fig. 3
Monthly mean mass concentrations of five air pollutants in Luzhou City.
Fig. 4
Comparison of air quality index values.
Fig. 5
Comparison of primary pollutants.
Fig. 6
Trends of the three air quality indexes in 2009.
Table 1
AQI and API Value, Description and Their Corresponding Mass concentration (μg/m3)
Value Grade Description AQI API

SO2 NO2 PM10 CO O3 SO2 NO2 PM10
0–50 I Good 50 40 50 2,000 100 50 80 50
51–100 II Moderate 150 80 150 4,000 160 150 120 150
101–150 III Unhealthy for sensitive people 475 180 250 14,000 215 475 180 250
151–200 IV Unhealthy 800 280 350 24,000 265 800 280 350
201–300 V Very unhealthy 1,600 565 420 36,000 800 1,600 565 420
301–500 VI Hazardous 2,620 940 600 60,000 2,620 940 600
Table 2
National Ambient Air Quality Standard in China
Air pollutants Average time Concentration limit(μg/m3) (GB3095-2012) Concentration limit(μg/m3) (GB3095-1996)

Grade I Grade II Grade I Grade II Grade III
Sulfur dioxide (SO2) Annual 20 60 20 60 100
24 h 50 150 50 150 250
1 h 150 500 250 500 700

Nitrogen dioxide (NO2) Annual 40 40 40 40 80
24 h 80 80 80 80 120
1 h 200 200 120 120 240

Particulate matter (PM10) Annual 40 70 40 100 150
24 h 50 150 50 150 250

Carbon monoxide (CO) 24 h 4,000 4,000 4,000 4,000 6,000
1 h 10,000 10,000 10,000 10,000 20,000

Particulate matter (PM2.5) Annual 15 35
24 h 35 15
Table 3
Comparison of the Air Pollutant Concentrations in Luzhou in 2009 with Other Cities (μg/m3)
City SO2 NO2 PM10 CO O3
Beijinga 34 53 121 1,600
Shanghaib 35 53 81
Guangzhouc 39 56 70
Chengdud 38 55 111
Luzhoue 59 40 72 2,017 54
Tokyof 6 43 23 500 4
Seoulg 14 72 54 750 26
Europeh 40 24 0.025 400 47

Beijing Environmental Protection Bureau

Shanghai Environmental Protection Bureau

Guangzhou Environmental Protection Bureau

Chengdu Environmental Protection Bureau

This study

Tokyo Bureau of Environment

Seoul Air Quality Management District

European Environmental Agency

Table 4
Correlation Analysis between Three Air Quality Indexes and the Air Pollutant Concentrations
Index Pollutant Regression equation R2 Standard deviation Significant coefficient
API SO2 y = 0.0010x-0.0039 0.6504 0.0161 0.806**
NO2 y = 0.0004x+0.0164 0.4948 0.0084 0.703**
PM10 y = 0.0018x-0.0368 0.9063 0.0123 0.952**

AQI SO2 y = 0.0010x-0.0095 0.5452 0.0184 0.738**
NO2 y = 0.0004x+0.0135 0.4377 0.0089 0.662**
PM10 y = 0.0018x-0.0506 0.8114 0.0174 0.901**
CO y = 0.0259x+0.2720 0.4087 0.6179 0.639**
O3 y = 0.0001x+0.0460 0.0058 0.0311 0.076

NAQI SO2 y = 0.0004x+0.0106 0.6626 0.0158 0.814**
NO2 y = 0.0002x+0.0218 0.5087 0.0083 0.713**
PM10 y = 0.0008x-0.0121 0.9335 0.0103 0.966**
CO y = 0.0086x+1.0588 0.3015 0.6715 0.549**
O3 y = −9.5×10−6x+0.0551 0.0002 0.0312 −0.016
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